I never really understood complimentary colours, which makes sense, because I did horribly on that section of Colour. It's an incredibly simple game that will drive you mad trying to get a perfect score.
Colour is from Method of Action, who host a course called Design For Programmers. As you might imagine, the course attempts to teach design concepts to "analytic and logical thinkers". It seems like Codecademy for design, and I can only assume it was created with the hope of reducing the number of "make me a logo for free" requests designers get. If the entire site is as engaging as Colour, they might actually achieve it.
Oh, and if you're colour-blind, don't worry! They have a colour-blind mode, as well as tablet support!